{"@context":"http://iiif.io/api/presentation/2/context.json","@id":"https://repo.library.stonybrook.edu/cantaloupe/iiif/2/manifest.json","@type":"sc:Manifest","label":"Thermal and Mechanical properties of Graphene/Polymer Nanocomposites","metadata":[{"label":"dc.description.sponsorship","value":"This work is sponsored by the Stony Brook University Graduate School in compliance with the requirements for completion of degree."},{"label":"dc.format","value":"Monograph"},{"label":"dc.format.medium","value":"Electronic Resource"},{"label":"dc.identifier.uri","value":"http://hdl.handle.net/11401/76364"},{"label":"dc.language.iso","value":"en_US"},{"label":"dc.publisher","value":"The Graduate School, Stony Brook University: Stony Brook, NY."},{"label":"dcterms.abstract","value":"We have successfully fabricated the PP/GNPs nanocomposites that are thermally conductive, processable, and flame resistant.  Thermal conductivity measurements indicated that the thermal coefficient scaled linearly with GNP loading, where a value of   2.0W/m*k was achieved at a loading of 40%.  Tensile measurement indicated that the modulus increased, linearly with GNPs loading, while the IZOD impact and toughness after an initial decrease, remained constant for loading up to 50%. The torque required for extrusion increased only by 25% over this range indicating that the compound remained processable despite the high loading content.  SAXS showed  a large  decrease in the amount of lamellar folding relative to the neat PP sample, while WAXS and  DSC measurements,  indicated   a slight increase in the degree of crystallinity .  These results are consistent with strong adsorption of the PP chains to the GNP, which, while maintaining crystallinity, disrupts the lamellar structure. Cone calorimetry showed that nanocomposites with 10% loading or higher exhibited a dramatic decrease in heat release and mass loss rates.  The time to ignition initially decreased relative to the neat PP, then increased and surpassed it by a factor of 2 at 40%. These results paralleled those from   conductivity/frequency measurements indicating that percolation occurred. Hence thermal phonon dissipation was effective for a slowly approaching heat front while contact was required for a rapidly approaching front."},{"label":"dcterms.available","value":"2017-09-20T16:50:06Z"},{"label":"dcterms.contributor","value":"Rafailovich, Miriam H"},{"label":"dcterms.creator","value":"Yang, Kai"},{"label":"dcterms.dateAccepted","value":"2017-09-20T16:50:06Z"},{"label":"dcterms.dateSubmitted","value":"2017-09-20T16:50:06Z"},{"label":"dcterms.description","value":"Department of Materials Science and Engineering."},{"label":"dcterms.extent","value":"136 pg."},{"label":"dcterms.format","value":"Monograph"},{"label":"dcterms.identifier","value":"http://hdl.handle.net/11401/76364"},{"label":"dcterms.issued","value":"2015-08-01"},{"label":"dcterms.language","value":"en_US"},{"label":"dcterms.provenance","value":"Made available in DSpace on 2017-09-20T16:50:06Z (GMT). No. of bitstreams: 1\nYang_grad.sunysb_0771E_12026.pdf: 4488708 bytes, checksum: 0473246fd60e248497496de407caba49 (MD5)\n  Previous issue date: 2014"},{"label":"dcterms.publisher","value":"The Graduate School, Stony Brook University: Stony Brook, NY."},{"label":"dcterms.subject","value":"Plastics"},{"label":"dcterms.title","value":"Thermal and Mechanical properties of Graphene/Polymer Nanocomposites"},{"label":"dcterms.type","value":"Dissertation"},{"label":"dc.type","value":"Dissertation"}],"description":"This manifest was generated dynamically","viewingDirection":"left-to-right","sequences":[{"@type":"sc:Sequence","canvases":[{"@id":"https://repo.library.stonybrook.edu/cantaloupe/iiif/2/canvas/page-1.json","@type":"sc:Canvas","label":"Page 1","height":1650,"width":1275,"images":[{"@type":"oa:Annotation","motivation":"sc:painting","resource":{"@id":"https://repo.library.stonybrook.edu/cantaloupe/iiif/2/15%2F32%2F26%2F153226289359581291151468169352595414541/full/full/0/default.jpg","@type":"dctypes:Image","format":"image/jpeg","height":1650,"width":1275,"service":{"@context":"http://iiif.io/api/image/2/context.json","@id":"https://repo.library.stonybrook.edu/cantaloupe/iiif/2/15%2F32%2F26%2F153226289359581291151468169352595414541","profile":"http://iiif.io/api/image/2/level2.json"}},"on":"https://repo.library.stonybrook.edu/cantaloupe/iiif/2/canvas/page-1.json"}]}]}]}